Good to Know

WHAT IS TEMPERATURE?

How to maintain the temperature of heat-sensitive health products?

Temperature is a characteristic of heat intensity. There are mainly 3 temperature reference systems:

  • The centigrade or Celsius scale: at atmospheric pressure at the coast, 0°C corresponds to melting and 100°C corresponds to boiling.
  • The Kelvin scale, whose lower limit 0 K corresponds to -273°C, is the absolute rest state of molecules. There is no agitation in the molecules of matter.
  • The Fahrenheit scale, the reference frame of which can be recalculated on the Celsius scale using the relationship T(°F) = 9/5 T(°C) +32

COLD. WHAT IS IT ALL ABOUT?

Cold is defined as the opposite of hot. More precisely, it is an absence of heat.

From a physical point of view, heat is a form of energy which causes the disorderly agitation of molecules within a substance. The more the matter is cold, the less the molecules are agitated and the matter is more solid. The more the matter is hot the more the molecules are agitated and the lighter the matter is. We will see further on that this impact on density makes warm air lighter than cold air.

This energy which we call heat, transmits itself from a hot matter to a cold matter. This transfer does not stop until the two matters share the same temperature.

Define cold: what is cold? how to produce it? how to maintain it?

HOW TO PRODUCE COLD? WHY ARE WE TALKING ABOUT ACTIVE COOLING AND PASSIVE COOLING?

Cold production is the process of absorbing heat. When we produce cold, we are actually absorbing heat from an item whose temperature therefore becomes lower.

Several physical phenomena can be used to produce cold. We present two of them to you.

THE EXPANSION OF A COMPRESSED GAS, THE PHENOMENON USED IN ACTIVE COOLING

We only observe this phenomenon when we use an aerosol. The compressed gas in the tank quickly expanded. This expansion is accompanied by a cooling that we feel when we touch the aerosol nozzle. On the other hand, when we inflate the tyres on a bicycle, we compress the gas. The bicycle pump becomes hot.
This phenomenon is used in the case of active cooling. A motor with an electrical or mechanical power source, compresses and expands a gas in a closed circuit. The part of the circuit where the expansion takes place cools the isothermal container. A conventional refrigerator works on this principal.

THE CHANGE IN STATE OF A MATTER, THE PHENOMENON USED IN PASSIVE COOLING

The material can be found in three states: solid, liquid and gaseous. At constant pressure, the material changes state by absorbing or releasing heat.

Therefore, when iced water melts, it absorbs heat to move from solid (ice) to liquid (water). This phenomenon is called fusion. The environment is then cooled.

It is this phenomenon that is used in passive cooling when the supply of previously frozen eutectic plates releases cold in an isothermal container.

Changes in state between solid and liquid make it possible to produce cold called passive cold

TO SUMMARISE

Active cooling uses a cooling unit that requires a continuous source of energy, either electric or using fuel.

Passive cooling uses an energy source such as a battery previously charged with cold: PCMs or eutectic plates.

WHY USE COLD SUPPLY WITH AN ISOTHERMAL CONTAINER?

As we have seen before, heat is an energy that is transmitted from a warm matter to a cold matter. The exchange only stops when both matters balance at the same temperature.

An isothermal material will slow down these heat intakes until the inside and outside environments are at the same temperature. Therefore, an isothermal container alone cannot maintain the stability of the desired temperature. A cold supply is necessary: active cooling, passive cooling or cryogenic cooling

CRYOGENIC COOLING OR THE SUBLIMATION OF DRY ICE

With the sublimation of dry ice associated with an isothermal container, COLD & CO maintains the temperature of frozen products

Dry ice is a material that, at atmospheric pressure passes directly from a solid to a gaseous state without passing through a liquid phase. This phenomenon is called sublimation. The ice is transformed directly into gas without leaving any trace at a temperature of -78.9°C. From a thermal point of view, sublimation absorbs a lot of heat and therefore cools its environment very efficiently.

WHAT IS AN ISOTHERMAL CONTAINER? HOW TO COMPARE USING LAMBDA AND THE COEFFICIENT K?

An isothermal container is a container whose insulated sides prevent heat from entering.

LAMBDA TO EVALUATE A MATERIAL

To evaluate the performance of an insulating material we use the value of the lambda thermal conductivity coefficient (λ) in W/m.K. The lower the λ, the more insulating the material.

The most commonly used materials in isothermal systems and their associated lambda values are as follows:

Lambda is used to measure the isothermal performance of materials.

The Coefficient K to evaluate a container

To evaluate the performance of an isothermal container, we use the value of the thermal transmission coefficient K in W/m.K which presents the loss of the container as a whole. The lower the value of the k coefficient, the more efficient the isothermal container is.

The coefficient K is used to measure the isothermal performance of an insulated container.

HEAT IS TRANSMITTED IN THREE WAYS

  • By conduction: the heat is transferred by molecule to molecule contact. We can feel this transmission when we heat a metal ruler at one end and feel the heat arrive at the other end. The agitation of the metal molecules has been conducted from one molecule to the next and therefore from one end of the ruler to the other. Air is often used as thermal insulation because it is a very poor conductor of heat and therefore a good insulator.

Therefore, insulation materials – such as polystyrene foams, polyurethane, glass wool or cotton wool – trap air in the form of a bubble. A vacuum being the best insulator. Since no molecules are present no thermal conduction is possible.

The coefficient K is used to measure the isothermal performance of an insulated container.
The coefficient K is used to measure the isothermal performance of an insulated container.
  • By radiation: heat is transmitted as an electromagnetic wave. We feel this phenomenon when we move from a shaded area into direct sunlight or when we are in front of an open fire. The parts of our body exposed to the sun or fire feel the heat whereas the part of the body which remained unexposed remains cool.

Materials with a silver/gold coating and a very smooth exposure surface reflect radiation and absorb only a small part of the heat. These materials guarantee good quality thermal insulation.

  • By convection: this phenomenon only concerns fluids (gas and liquid). The difference in fluid density associated with gravity results in a less dense and ‘lighter’ upward movement of the hot fluid when the denser, lower fluid falls. We observe this phenomenon in a pan of heated water. The water is moving.

Insulating foams prevent heat transmission by convection since no air movement is created between the trapped air bubbles of the structure. The convection phenomenon is created from a certain distance between the hot and cold fluid. A short distance such as in double glazing, where the air gap between the two panes does not exceed 2cm, no thermal convection is possible.

The coefficient K is used to measure the isothermal performance of an insulated container.

WHAT IS A PCM? WHAT IS A EUTECTIC?

PCM is an acronym for Phase Change Material.

A PCM is a material that, under the effect of temperature, changes from a solid to a liquid state (and vice versa) while maintaining the same temperature. PCMs therefore store energy in the form of latent heat. Heat is absorbed or released when the solid state changes to the liquid state.

It is this battery phenomenon that we use in passive cooling to cool an isothermal container. This results in keeping the isothermal container cold or cooling.

The PCMs can be classified into three main categories:

NF S 99 -700 qualified solution of a Diagnocase Pharma Precision isothermal container with PCM + 5 eutectic packs to maintain the temperature of thermosensitive health products over a range of 2 ° C - 8 ° C.

Organic PCMs

These are paraffin and fats. They have the advantage of offering a wide range of holding temperatures but their latent heat relative to volume is rather limited.

Inorganic PCMs

These are mainly hydrated salts. Their latent heat relative to volume is high but the temperature for the holding phase (solid and liquid) of the cooling may be more unstable.

Eutectic PCMs

This is a mixture of at least 2 pure matters (organic or not). The resulting melting point temperature is lower than that of either the two substances that have been mixed. The most well-known eutectic is the water + salt eutectic (H20 + NaCl) often used on icy roads to lower the melting point temperature of the ice.

WHICH PCM TO CHOOSE?

Choose the gel pack or eutectic plate that restores the temperatures adapted to your products. Do not hesitate to contact us to advise you.

Eutectic plates provide specific temperatures. How to choose your gel pack or eutectic plate to maintain the temperature of its products?
Type of liquide Restored temperature  Recommended freezing temperature Freezing time
 

PCM-26

 

-30°C à -22°C

 

maximum -34°C

 

minimum 48h

 

PCM-21

 

-27°C à -21°C

 

maximum -18°C

 

minimum 48h

 

PCM -3

 

0°C à +6°C

 

maximum -18°C

 

minimum 48h

 

PCM 0

 

0°C à +12°C

 

maximum -18°C

 

minimum 48h

 

PCM 5

 

2°C à 8°C

 

0°C maximum in summer

12°C minimum in winter

 

minimum 48h

 

PCM 20

 

15°C à 25°C

 

4°C maximum in summer

30°C minimum in winter

 

minimum 48h

AT WHAT TEMPERATURE SHOULD THE EUTECTIC / PCM PLATES BE PREPARED?

Fresh and frozen products

To maintain the temperature of fresh and frozen products, we recommend to condition PCM 0, PCM-3 and PCM-21 for a minimum of 48 hours at a maximum temperature of -18°C.

The PCM-26 will be conditioned at a maximum temperature of -34°C for a minimum of 48 hours.

Favour a distribution of the plates on the shelf to allow the cold air to circulate and facilitate their cooling.

Instructions fresh and frozen eutectic plates
Gel packs and eutectic plates are refrigerants that must be frozen before use. Promote their freezing by placing them on the shelf to allow air to circulate.

pharmaceutical products range 2°C to 8°C

Specifically designed for temperature-sensitive health products in the +2°C / +8°C temperature range, the PCM+5 eutectic packs are used regardless of the season thanks to their heating and cooling modes.

If the average outside temperature is >8°C, use the solid state packs in cooling mode.

We recommend charging them at least 24h between -15°C and -30°C in order to obtain a solid state. To avoid cold peaks, stabilize the plates between -2°C and 0°C before introduction into the package, leaving them at room temperature between 30 minutes (for freezing at -15°C) and 45 minutes (for freezing at -30°C).

If the outside temperature is on average <2°C, use the packs in the liquid state, in warm-up mode.

We recommend charging them at a minimum of 24 hours at a temperature above 12°C in order to obtain a liquid state. Then, 12 hours before entering the package, stabilize the plates at +5°C.

PCM +5 ​​eutectic pack to maintain the temperature of thermosensitive health products over a range of 2 ° C - 8 ° C in summer.
PCM +5 ​​eutectic pack to maintain the temperature of thermosensitive health products over a range of 2 ° C - 8 ° C in winter.
Instructions eutectic plates PCM+5

Pharmaceutical products range 15°C to 25°C

Specifically designed for temperature-sensitive health products in the +15°C / +25°C temperature range, the PCM+20 eutectic packs are used regardless of the season thanks to their heating and cooling modes.

If the average outside temperature is >25°C, use the solid state packs in cooling mode.

We recommend loading them at a minimum of 48h at a temperature below 4°C in order to obtain a solid state. Before entering the packaging, stabilize the plates at room temperature between 30 and 45 minutes.

If the outside temperature is on average <15°C, use the packs in the liquid state, in warm-up mode.

We recommend that you first load them at least 48 hours in an oven at a temperature between 30°C and 40°C in order to obtain a liquid state. Then, 12 hours before introduction into the package, stabilize the plates at room temperature between 30 and 45 minutes.

Flexible gel packs, absorbent gel packs, solid gel packs, plates… How do you find your way around?

Gel packs and eutectic plates are refrigerants that must be frozen before use. Promote their freezing by placing them on the shelf to allow air to circulate.

PCMs, eutectics, and gel packs are packaged in different ways. We will present you with the most commonly used for you to choose from, depending on your needs.

  • Flexible gel packs, also known as gel packs are flexible bags made up of an opaque or transparent film containing eutectic or PCM in gel form. These packs are lighter and more economical than a rigid pack due to the saving made from not having a rigid shell. However, they must be frozen flat to give them a homogenous frozen shape.
  • Absorbent flexible gel packs are flexible gel packs whose film making up the pouch is made of absorbent material. Therefore, the condensation and water drops that appear when melting conventional gel packs, are absorbed by this woven coating. We recommend this coating to protect heat sensitive products from moisture. As with traditional flexible gel packs they should be frozen flat to give them a homogenous frozen shape.
Gel packs and eutectic plates are refrigerants that must be frozen before use. Promote their freezing by placing them on the shelf to allow air to circulate.
Gel packs and eutectic plates are refrigerants that must be frozen before use. Promote their freezing by placing them on the shelf to allow air to circulate.
  • Rigid gel packs have a rigid outer shell often made of high-density polyethylene (HDPE) to resist impact, compression and puncture. These shells are then filled with the desired eutectic liquid or PCM and sealed with a crimped cap. They are available in a variety of different sizes and weights from 250g to 1kg.
  • Eutectic plates have the same characteristics as rigid gels. With weights ranging from 2kg to 4kg, eutectic plates have more standardised sizes called Gastronorm. Currently we find:> GN 1/1 plates with dimensions 530 x 325 x 30 mm

> GN 1/1 plates with dimensions 530 x 325 x 30 mm

> GN 1/2 plates with dimensions 325 x 265 x 30 mm

Gel packs and eutectic plates are refrigerants that must be frozen before use. Promote their freezing by placing them on the shelf to allow air to circulate.

HOW AND FOR HOW LONG SHOULD THE PCM AND EUTECTIC PLATES BE RECONDITIONED?

Check your freezing with eutectic plates and refrigerants

We recommend a minimum reconditioning time of 48 hours for PCMs. A PCM is fully reconditioned when all the liquid in the PCM has become solid. To check it is frozen to the core, the PCM can be shaken. If we feel that it is still in a liquid or semi-liquid state, then the eutectic solution is not fully charged.

To accelerate conditioning, the eutectic plates must be separated from each other inside the freezing chamber. Stacked storage or packing them in cardboard boxes or on pallets prevents the circulation of cold air and considerably increases their freezing time. It takes up to 1 week to freeze the eutectic plates to the core.

To facilitate the efficient conditioning of the PCM and eutectic plates we recommend the use of plate distribution trolleys or shelves to organise and spread out the eutectic plates.

To speed up the conditioning of your eutectic plates, distribute your PCM plates, eutectics and gel packs on shelves or trolley to promote air ventilation.
A double set of plates makes it possible to rotate between eutectic plates during recharging and eutectic plates during use.

To ensure the plates are always available, a double set of eutectic plates makes it possible to set up a system of rotation: when one set of plates is being used the other set is being recharged.

WHAT IS ECO-RESPONSIBLE URBAN DISTRIBUTION?

An eco-responsible urban distribution consists of a system reducing the nuisances associated with the transport of goods:

  • Reduction of gases, pollutants and particles related to fuel consumption to improve air quality.
  • Reduction of noise pollution.
  • Relieving traffic congestion by pooling transport, developing night deliveries, deliveries by electric mopeds or bicycles and multimodal deliveries.

Environmental policies establish Restricted Traffic Zone (RTZ) with the identification of vehicles according to the CRIT’Air stickers.

At COLD & CO, our CarryTemp solutions are noiseless and autonomous from an energy point of view. Moreover, they can easily adapt to clean and new last miles vehicle: cargo bike, electrical scooter, electrical or CNG (Compressed Natural Gas) vehicle.

Insulated container compatible for eco-responsible bike delivery or cycle of fresh products in the city center.

PIEK certificationfor silent delivery

PIEK certification is required for night deliveries. It certifies that the equipment meets the maximum sound threshold of 60dB(A) at 7,5 metres for deliveries between 23:00 and 07:00.

Piek certification has been adopted in several countries such as the United Kingdom, France, Germany and Belgium.

Since 2012, the city of Paris has been a member of the CERTIBRUIT association, which provides urban logistics stakeholders and local authorities with global support to carry out night deliveries that respect local residents.

Since April 2018, the city of Paris is also subsidizing carriers and small traders who purchase clean and quiet vehicles certified by Piek.

Piek marking is a marking attributed to equipment, including containers, which contribute to the reduction of noise generated by night deliveries, and to the respect of residents.

The ATP, WHAT SHOULD I KNOW?

Piek marking is a marking attributed to equipment, including containers, which contribute to the reduction of noise generated by night deliveries, and to the respect of residents.

ATP is an acronym for ‘the Agreement on the International Carriage of Perishable Foodstuffs and on the Special Equipment to be used for such Carriage’. This United Nations treaty, which entered into force in 1976, was signed by 48 countries.

In European countries having contracted the ATP, the transport of perishable foodstuffs is subject to two types of regulation:

  • An obligation to achieve results: the food must be transported at the temperature indicated in the legislation.
  • A duty of care requiring the use of a transport system with a certificate of ATP technical conformity. The text is available here: Text of the ATP Agreement on UNECE website.

The ATP sets out the thermal insulation and refrigeration performance requirements necessary to transport perishable foodstuffs. This obligation may be waived for transport of less than 80km without reloading i.e. without opening the doors of the refrigerated unit.

In other words, the distribution of perishable foodstuffs for a distance of less than 80km and with several delivery points must:
1. Justify correct temperatures for maintaining perishable foodstuffs;
2. Use ATP approved solutions, insulating sufficiently and with good refrigeration capacity.

For example, the COLD & CO CarryTemp  have been granted ATP approval as a class C and D reinforced refrigerated vehicle.

Temperature STANDARDS

Attention, there is no substitute for the responsibility of the customer transport provider to designate the appropriate transport temperature of its products.

TEMPERATURE CONDITIONS TO BE OBSERVED FOR THE CARRIAGE OF CHILLED FOODSTUFFS

Temperature conditions to be observed for the carriage of chilled foodstuffs

TEMPERATURE CONDITIONS TO BE OBSERVED FOR THE CARRIAGE OF QUICK (DEEP)-FROZEN AND FROZEN FOOSTUFFS

Temperature conditions to be observed for the carriage of quick (deep)-frozen and frozen foodstuffs

HOW TO BENEFIT FROM AN ATP CERTIFICATE?

To benefit from an ATP certificate each isothermal container and each cooling device is subjected to a test in an official ATP test station.

This test is used to qualify:

1. THE ISOTHERMAL EFFICIENCY OF THE EQUIPMENT

A measure of the coefficient K, insulation coefficient, determines the isothermal quality of the equipment:

the isothermal efficiency of an insulated container is defined by the value of its coefficient K

2. THE EFFICIENCY OF COOLING DEVICES

For an outside temperature of 30°C, a refrigerating unit will be classified into 4 classes if it lowers and maintains the inside temperature for more than 12 hours:

the efficiency of an insulated container is defined by its temperature maintenance

For example, COLD & CO CarryTemp containers have obtained the ATP agreement as a reinforced class C and D refrigerated unit.

ATP LABELLING

To identify the permitted temperature ranges and the validity period of the approval, an ATP label with a minimum size of 160x100mm is attached to the equipment.
For example this ATP label on a COLD & CO CarryTemp box indicates that it is a reinforced isothermal unit or a reinforced refrigeration unit – if combined with eutectic plates – of class C.
This CarryTemp container was assembled in June 2019 and its first 6-year approval is valid until June 2025.

COLD & CO explains what an ATP label is
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